Comparative thermodynamic analysis and phase diagram prediction of the Ga – Sn – Zn system

Abstract

AbstractThe results of comparative thermodynamic analysis and phase diagram prediction of the Ga – Sn – Zn system are presented in this work. The thermodynamic study was done experimentally – using Oelsen calorimetry, for the section Ga – SnZneut, and analytically – according to the general solution model, for the whole system. Main thermodynamic quantities – integral and partial molar Gibbs excess energies, activities and activity coefficients were calculated over a wide temperature range. Additionally, the phase diagram of the section Ga – SnZneut was investigated using differential thermal analysis and predicted using the CALPHAD method. Comparison with available literature data showed reasonable agreement. The liquidus projection of the ternary Ga – Sn – Zn was also calculated.