This research investigated the relationships of the Dark Triad, impulsiveness, and social network sites (SNS) addiction with adolescents. In particular, this research examined the indirect effects of the measured motor, attentional, and nonplanning impulsiveness on the relationship of the Dark Triad and SNS addiction. To examine the possible antecedents of SNS addiction, 169 adolescents aged 14-17 were recruited for this research. After obtaining informed consents from their legal guardians, these adolescents completed the Dirty Dozen, the modified Bergen Facebook Addiction Scale, and the Barratt Impulsiveness Scale – version 11. Results showed that the Dark Triad composite score was positively correlated with SNS addiction and the different aspects of impulsiveness, while SNS addiction was positively correlated with motor impulsiveness. The indirect effect of motor impulsiveness on the relationship of the Dark Triad and SNS addiction was significant. The present findings provide theoretical insights to the development of SNS addiction.