DETERMINATION OF SELECTED ATMOSPHERIC AMINES IN THE PRESENCE OF INORGANIC CATIONS BY ISOCRATIC ION CHROMATOGRAPHY

Author:

Pecyna-Utylska Paulina1,Michalski Rajmund1

Affiliation:

1. Instytut Podstaw Inżynierii Środowiska Polskiej Akademii Nauk w Zabrzu

Abstract

The aim of this study was to optimize and validate the methodology for the determination ofselected aliphatic amines in the presence of inorganic cations in environmental samples (rainwater,snow, particulate matter) by isocratic ion chromatography with suppressed conductometricdetection. The obtained detection limits for selected aliphatic amines were 4.65 g/L, 4.46 g/L,and 12.4 g/L for methylamine, dimethylamine, and trimethylamine, respectively. The relativestandard deviation of repeatability for real samples was less than 6%. The recovery was within therange of 90.3%100%. The developed methodology was applied to analyse wet deposition andparticulate matter samples.

Publisher

Index Copernicus

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