Electrodeposition of FeCrNi and FeCr alloys and influence of heat treatment on microstructure and composition

Abstract

Abstract The electroplating of iron-chromium and iron-nickel-chromium layers is an economic alternative to mild steel and hard-chrome layers from chromium (VI) electrolytes. Iron-chromium and iron-nickel-chromium layers were electrodeposited using an environment friendly chromium (III) electrolyte. The layers were heat-treated at different temperatures (150 °C, 300 °C, 450 °C and 600 °C) in order to determine the temperature at which recrystallization takes place, which phases are formed and to study the influence on the element content. The phase analysis was conducted by X-ray diffraction, the chemical composition and the microstructure were characterized by the scanning electron microscopy. Both layer systems show an X-ray-amorphous structure that begins to recrystallize at a temperature of 450 °C. From a heat-treatment temperature of 600 °C, the organic additives decompose and the oxygen forms chromium oxide with the chromium.