Activation energy and crystal growth coefficient determination of t-ZrO2 using high-temperature synchrotron X-ray diffraction

Abstract

Abstract Activation energy and crystal growth coefficient of t-ZrO2 (tetragonal zirconia) were determined through an in-situ synchrotron radiation X-ray diffraction (SR-XRD) experiment. The t-ZrO2 precursor was synthesized through (a) purification of zircon sand from Kereng Pangi, Kalimantan to zircon powder, (b) alkali fusion, and (c) co-precipitation. High-temperature SR-XRD experiments were carried out with varying holding times of 1, 2, and 3 hours at 900, 950, and 1000 °C, respectively, where the formation and crystal growth of t-ZrO2 were observed. The diffraction patterns show that t-ZrO2 has formed at 900°C for 1 hour and it grows accordingly. The effect of the heating temperature and holding time on the crystal growth shows that the size of hot crystals increases with increasing temperature and holding time. It is found that the activation energy of t-ZrO2, in general, decreases with holding time, i.e. from 75.3 kJ/mol (3 h) to 57.3 (1h). Meanwhile, Beck’s crystal growth coefficient value is between 0.3 at 900 °C and 0.2 at 1000 °C.