Strong Ferromagnetic Coupling of {[Cu(Hpht)(N 3 )]·H 2 O} n with Simultaneous End-on Azido and Carboxylato Bridges: a First Principle Study
Author:
Publisher
IOP Publishing
Subject
Physics and Astronomy (miscellaneous)
Link
https://iopscience.iop.org/article/10.1088/0253-6102/43/2/030/pdf
Reference16 articles.
1. Magnetostructural Correlations in .mu.2-1,1-N3 Bridged, Dinuclear Copper(II) Complexes. 1. Ferromagnetic and Antiferromagnetic Coupling Associated with the Azide Bridge. X-ray Crystal Structures of [Cu2(DMPTD)(.mu.2-N3)(.mu.2-Cl)Cl2].cntdot.CH3CN, [Cu2(DMPTD)(.mu.2-N3)2(N3)2], [Cu2(DIP)(.mu.2-N3)(.mu.2-Cl)Cl2].cntdot.0.5CH3OH, [Cu2(PAP46Me-H)(.mu.2-N3)(N3)2].cntdot.0.33H2O, [Cu2(PAP)(.mu.2-N3)Cl3].cntdot.CH2Cl2, [Cu2(PAP)(.mu.2-N3)(N3)(NO3)(CH3OH)](NO3).cntdot.CH3OH, [Cu2(PPD3Me)(.mu.2-N3)Cl3(H2O)1.5], and [Cu2(PPD)(.mu.2-N3)(NO3)3(H2O)1.6]
2. Magneto-structural correlations in .mu.2-1,1-azide-bridged dicopper(II) complexes. 2. Dominant antiferromagnetic coupling with azide bridge angles exceeding 108.degree.. X-ray Structures of [Cu2(PAP)(.mu.2-N3)Br3].cntdot.CH2Cl2, [Cu2(PAP6Me)(.mu.2-N3)(.mu.2-Br)Br2].cntdot.1.68H2O, [Cu2(PAP6Me)(.mu.2-N3)(.mu.2-H2O)(NO3)2](NO3).cntdot.0.75CH3OH, [Cu2(PAN)(.mu.2-N3)(.mu.2-NO3)(NO3)2].cntdot.CH3OH.cntdot.CH3CN, and [Cu2(PPD35Me)(.mu.2-N3)Br3(CH3OH)]
3. Dinuclear copper(II) cryptates of macrocyclic ligands: synthesis, crystal structure, and magnetic properties. Mechanism of the exchange interaction through bridging azido ligands
4. Crystal structure and magnetic and EPR properties of bis(.mu.-azido)tetrakis(4-tert-butylpyridine)dicopper(II) perchlorate: a new copper(II) dinuclear complex with a large stabilization of the ground triplet state
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