Impacts of stratosphere-to-troposphere transport on tropospheric ozone in southeastern China: insights from ozonesonde observations

Abstract

Abstract Tropospheric ozone pollution poses a major environmental challenge in China. As its primary natural source, Stratosphere-to-Troposphere Transport (STT) has been recognized as a significant contributor to tropospheric ozone in western, northeastern, and eastern China. However, the extent of STT’s influence on southeastern China has been less studied due to data limitations. Using a recently available one-year dataset of ozonesonde observations from a regional background station, we find that STT contributes significantly to tropospheric and surface ozone elevation in southeastern China. Our results show that STT plays a more substantial role in shaping tropospheric ozone during spring than previously believed, accounting for over 30% of ozone concentrations above 4 km. Without the stratospheric contribution, the spring seasonal peak almost disappears. STT can also significantly influence ozone concentrations at the surface. For example, a distinct ozone profile was observed on 4 May 2022, with a notable increase in tropospheric ozone. This tropospheric ozone increase was caused by a STT event triggered by a robust horizontal trough and subsequent southward movement of subtropical jets in the upper troposphere. According to a stratospheric tracer derived from an atmospheric chemistry model, this STT event contributed to 25%–30% of the surface ozone increase. Overall, this study highlights the important role of STT in driving tropospheric ozone variations, even in regions with comparatively lower ozone levels in southeastern China.