Structural, dielectric, impedance, complex modulus, and optical study of Ni-doped Zn(1−x)NixO nanostructures at high temperatures

Abstract

Abstract This experiment addressed the effect of Nickel-doped on the dielectric, ac conductivity, and optical properties of pure and doped Zn (1−x) Nix O (x = 0, 3 and 6%) nanostructures. The un-doped and Ni-doped ZnO nanostructures were synthesized using co-precipitation. In this paper, the frequency-dependent dielectric and the electrical conductivity of un-doped and Ni-doped Zn (1−x) Nix O nanostructures were examined at various temperatures ranging from 320 K to 460 K using an LCR meter. For the morphological and optical investigation, the prepared samples were analyzed using field emission-scanning electron microscopy (FE-SEM), and UV visible Spectroscopy was used at room temperature. The dielectric constant ( ε ′ ), dielectric loss ( ε ″ ), tangent loss (tan δ), the real as well as the imaginary part of the impedance against the frequency ranging from 100 Hz to 2 × 106 Hz that declines with increases in frequency at different temperatures ranging from 320–460 K. However, the electrical conductivity ( σ a c ) increased with the increase in frequency was examined. The ac conductivity ( σ a c ) follows Jonscher,s power law that the electrical conductivity is enhanced with increasing doping concentration. The optical transmission area also improved due to an increase in Ni-doping concentration in ZnO. The optical bandgap of pure and Ni-doped ZnO nanostructures is in the range lies 3.30–3.12 eV found that to decrease with the increase in Ni doping concentrations.