Adsorptive removal of congo red dye from aqueous solutions using Mo-doped CoFe2O4 magnetic nanoparticles

Abstract

Purpose The main purpose of this paper is to investigate the adsorption properties of CoFe1.9Mo0.1O4 magnetic nanoparticles (CFMo MNPs) using, anionic dye “congo red (CR)” as a model of water pollutants. Design/methodology/approach The magnetic nano-adsorbent was synthesized via sol-gel process. Different techniques including; Fourier transform infrared spectroscopy, point of zero charge, scanning electron microscope and X-ray powder diffraction were used to characterize the prepared adsorbent. Adsorption experiments were conducted in batch mode under various conditions (contact time, shaking speed, initial dye concentration, initial solution pH, solution temperature and adsorbent amount) to investigate the adsorption capability of CFMo MNPs for CR. Findings The results showed that, CFMo MNPs could successfully remove more than 90% of CR dye within 20 min. Adsorption kinetics and isotherms were better described using pseudo-second-order (PSO) and Langmuir models, respectively. The maximum adsorbed amount (qmax) of CR dye was 135.14 mg/g. The adsorption process was found to be endothermic and spontaneous in nature as demonstrated by the thermodynamics ( ΔGo, ΔHoand ΔSo). Practical implications This study provided a good example of using an easily separated magnetic nano-adsorbent for fast removal of a very toxic organic pollutant, congo red, from the aquatic environment Originality/value The employment of Mo-doped cobalt ferrite for the first time for removing hazardous anionic dyes such as congo red from their aqueous solutions.