The collision cross-sections for proton–argon interaction based on ab initio potential

Abstract

The classical collision cross-sections of a proton with an argon atom as well as the thermal transport coefficients and rate constant of the colliding $\text{H}^{+}-\text{Ar}$ system are evaluated at the kinetic temperature $T\in [100,10\,000]~(\text{K})$ by means of the asymptotically correct analytical potential constructed for the ground $X^{1}\unicode[STIX]{x1D6F4}^{+}$ state of the ArH+ cation from the highly accurate ab initio data available in the entire range of internuclear distances (Terashkevich et al., J. Quant. Spectrosc. Radiat. Transfer, vol. 234, 2019, pp. 139–146). The results can be useful to estimate thermodynamic, transport and kinetic properties of the Ar/H2 plasma in a wide temperature range.