Research on catalytic denitrification by zero-valent iron (Fe0) and Pd-Ag catalyst

Abstract

This study primarily focused on how to effectively remove nitrate by catalytic denitrification through zero-valent iron (Fe0) and Pd-Ag catalyst. Response surface methodology (RSM), instead of the single factor experiments and orthogonal tests, was firstly applied to optimize the condition parameters of the catalytic process. Results indicated that RSM is accurate and feasible for the condition optimization of catalytic denitrification. Better catalytic performance (71.6% N2 Selectivity) was obtained under the following conditions: 5.1 pH, 127 min reaction time, 3.2 mass ration (Pd: Ag), and 4.2 g/L Fe0, which was higher than the previous study designed by single factor experiments and orthogonal tests, 68.1% and 68.7% of N2 Selectivity, respectively. However, under this optimal conditions, N2 selectivity showed a mild decrease (69.3%), when the real wastewater was used as influent. Further study revealed that cations (K+, Na+, Ca2+, Mg2+, and Al3+) and anions (Cl-, HCO3-, and SO42-) exist in wastewater could have distinctive influence on N2 selectivity. Finally, the reaction mechanism and kinetic model of catalytic denitrification were further studied.