Use of chemically activated termite feces a low-cost adsorbent for the adsorption of norfloxacin from aqueous solution

Abstract

Abstract Antibiotics, as emerging contaminants, are of global concern due to the development of antibiotic resistant microorganisms. Current wastewater treatment technology cannot efficiently remove sewage antibiotics and therefore new low-cost technologies are needed. Adsorption is a widely used process for removal of substances, and the search for efficient, low-cost adsorbents is ongoing. In this work, termite feces treated with H2SO4 (FT/H2SO4) were used as a low-cost adsorbent for removal of norfloxacin (NOR) present in aqueous medium. Termite feces were treated with H2SO4 at a ratio of 1:1 for 24 h, at 100 °C. The parameters contact time, initial NOR concentration, medium pH and temperature were evaluated. The optimum adsorption pH was 8.0. The pseudo-second-order model was found to best represent the kinetics of NOR adsorption. The maximum adsorption capacity, calculated from the Sips isotherm model, was 104.4 mg/g at 55 °C. The positive values of ΔH0 (change in enthalpy) confirm the endothermic nature of the adsorption. The results show that FT/H2SO4 is an efficient adsorbent for removal of NOR present in aqueous medium. The adsorption capacity is higher than those reported in the literature for other low-cost adsorbents.