Complex Concentrated Alloy Catalyst of AlCrFeCoNi for Heterogeneous degradation of Rhodamine B

Author:

Sembiring Kiky Corneliasari1ORCID,Fahrezi Irgi Ahmad2,Muhdarina Muhdarina2,Afandi Ahmad3

Affiliation:

1. Research Center for Chemistry - BRIN, Building 452 KST BJ Habibie, Serpong, Tangerang Selatan 15314, Indonesia

2. Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Riau, Kampus Bina Widya, Km 12.5, Pekanbaru, Riau, Indonesia

3. Research Center for Advanced Materials - BRIN, Building 442 KST BJ Habibie, Serpong, Tangerang Selatan 15314, Indonesia

Abstract

The Fe-based catalysts have attracted good attention due to their earth abundance and low toxicity with good Fenton-like performance. However, the narrow pH working range and iron-containing sludge produced during the reaction drove the necessary of developing a potential catalyst in the corresponding application. High entropy alloy that now expands to complex concentrated alloy (CCA) represents a new class of material owing to a broader range of functional and structural properties. A new application of CCA as a catalyst for catalytic degradation of azo dyes has already been a scientific research hotspot. AlCrFeCoNi CCA powder has been successfully synthesized by mechanical alloying (MA) method using a vertical planetary ball mill. Based on the characterization, the catalyst possessed a spherical morphology with a particle size range of 3.5-12.6 mm. The catalyst exhibited photo-Fenton performance up to 85.3% which would be a promising Fenton-like catalyst for wastewater treatment. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Funder

Badan Riset dan Inovasi Nasional

Publisher

Bulletin of Chemical Reaction Engineering and Catalysis

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