Affiliation:
1. College of Chemistry, Jilin Normal University, Siping 136000, P.R. China
2. Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Abstract
Abstract
A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu2(L)(1,3-BDC)]
n
(1), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-H2BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X-ray diffraction analysis and powder X-ray diffraction. The crystals are the monoclinic space group P21/c with a = 10.686(4), b = 17.376(8), c = 11.759(4) Å, β = 92.072(14)°, C27H14Cu2FN4O4, M
r = 604.50, V = 2182.1(15) Å3, Z = 4, D
calcd. = 1.84 g cm–3, R = 0.0588 and wR = 0.1202 (all data). In complex 1, the mixed-valence Cu(I)/Cu(II) atoms are linked by L and 1,3-BDC to give a rare 3D (3,3,4)-connected (4.7.9)(7.8.9)(4.7.8.93) framework. The temperature-dependent magnetic susceptibility of 1 was investigated in the temperature range of 2–300 K.
Reference32 articles.
1. O. M. Yaghi, H. Li, J.Am. Chem. Soc. 1995, 117, 10401.
2. J. H. K. Yip, J. Wu, K.-Y. Wong, K.-W. Yeung, J. J. Vittal, Organometallics2012, 21, 1612.
3. H.-Y. Liu, J. Yang, Y.-Y. Liu, J.-F. Ma, Dalton Trans. 2012, 41, 9922.
4. J. Tao, M.-L. Tong, X.-M. Chen, J Chem Soc. Dalton Trans. 2000, 20, 3369.
5. G.-G. Gao, L. Xu, X.-S. Qu, H. Liu, Y.-Y. Yang, Inorg. Chem. 2008, 47, 3402.
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