Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6-Reference-Cited by-同舟云学术

Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6

Published:2018-02-01 Issue:2 Volume:73 Page:85-89
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Fu Shan¹,Fu Bo¹,Zhao Zhen¹,Liu Xi¹

Affiliation:

1. Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry , Chongqing Normal University , Chongqing 401331 , P.R. China

Abstract

Abstract The investigation of the supramolecular interactions between the lithium isothiocyanate salt and 18-crown-6 (18C-6) in commercial tetrahydrofuran leads to the formation of a lithium compound, LiNCS(H2O)(18C-6) (1). In the crystal structure the asymmetric unit contains two similar LiNCS(H2O)(18C-6) molecules. Solid-state photoluminescence experiments have shown that compound 1 emits violet luminescence, and its possible emission mechanism was investigated in detail based on theoretical calculations.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2017-0171/pdf

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