Notizen: New Phase Transitions in CsHSeO4, CsH2PO4, RbHSO4, RbHSeO4, and RbH2PO4

Author:

Baranowski B.12,Friesei M.1,Lundén A.1

Affiliation:

1. Department of Physics, Chalmers University of Technology, Göteborg, Sweden

2. Institute o f Physical Chemistry, Polish Academy o f Sciences, ul Kasprzaka 44/52, 01-224 Warszawa, Poland.

Abstract

Alkali metal hydrogen double salts can have more than one stable phase at ambient temperature. These phases can be identified by the enthalpy and temperature o f the endothermic phase transitions they undergo when heated. Transitions to these phases at ambient temperature depend on mechanical treatment (grinding, one-dimensional pressure) as well as on the water vapour pressure above a sample. Eight phase transitions (o f which five were not known before) have been studied by means o f differential scanning calorimetry.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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