Waste poly (vinyl chloride) pyrolysis with hydrogen chloride abatement by steelmaking dust

Author:

Korpas Jakub,Slovák Václav,Wichterle Kamil

Abstract

AbstractExperimental study on PVC-based materials (PVC = poly (vinyl chloride)) pyrolysis; in the presence of various amounts of steelmaking dust was performed. Dust from steel manufacture employing zinc plated scrap contains a considerable amount of zinc oxide (ZnO) and its utilization in metallurgy is quite complicated. However, the dust can react with hydrogen chloride (HCl) released from heated PVC in the temperature range of 200–400°C. Material balance of the pyrolysis process was studied by thermogravimetry, and the data obtained were compared with the results of larger laboratory oven experiments. In excess of PVC, the amount of captured HCl stoichiometrically corresponds to the content of ZnO; additional HCl is probably captured by FeCl

Publisher

Springer Science and Business Media LLC

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,General Chemical Engineering,Biochemistry,General Chemistry

Reference12 articles.

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