Zur Silylierung bifunktioneller Amidine der Oxalsäure / On the Silylation of Bifunctional Amidines of Oxalic Acid-Reference-Cited by-同舟云学术

Zur Silylierung bifunktioneller Amidine der Oxalsäure / On the Silylation of Bifunctional Amidines of Oxalic Acid

Published:1993-10-01 Issue:10 Volume:48 Page:1386-1390
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Beckert Rainer¹,Vorwerk Steffen¹,Lindauer Dirk¹,Döring Manfred²

Affiliation:

1. Institut für Organische Chemie und Makromolekulare Chemie der Friedrich-Schiller-Universität Jena, Humboldtstraße 10, D-07743 Jena

2. Institut für Anorganische und Analytische Chemie der Friedrich-Schiller-Universität Jena, August-Bebel-Straße 2, D-07743 Jena

Abstract

Ν,N′,N″,N‴-Tetraaryl-oxalic amidines react with N-trimethylsilyldiethylamine to yield the activated and open chained derivatives 3a, b. By the use of diorganyldichlorosilanes the new 1,3-diaza-2-sila-cyclopentanes 5a-d were obtained. Cycloacylations of 3a with geminal dichlorides are leading to different kinds of heterocyclic compounds

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1993-1013/pdf

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