The Rotational Spectrum and Nuclear Quadrupole Coupling of CH35C1F2

Author:

Blanco Susana1,Lesarri Alberto1,López Juan C.1,Alonso José L.1,Guarnieri Antonio2

Affiliation:

1. Departamento de Quimica Fisica, Facultad de Cieneias, Universidad de Valladolid, E-47005 Valladolid

2. Institut für Physikalische Chemie der Universität Kiel, Olshausenstr. 40, D-25098 Kiel

Abstract

Abstract The rotational spectrum of CH35CIF2 in the ground vibrational state has been measured in the frequency range 8-18 GHz using a waveguide Fourier transform microwave (FTMW) spectrometer in order to determine accurate nuclear quadrupole coupling constants. The spectra of the excited vibrational states ν5 = 1, ν6 = 1 and ν9 = 1 have been also observed and analyzed in the frequency region 8-250 GHz using FTMW, Stark, and source modulation spectrometers. Quadrupole coupling constants are also reported for these states.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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