Tris(1,10-phenanthroIine)iron(II) Complexes. Influence of 4,7-Donor Substitution on the Redox Potential [1]-Reference-Cited by-同舟云学术

Tris(1,10-phenanthroIine)iron(II) Complexes. Influence of 4,7-Donor Substitution on the Redox Potential [1]

Published:1994-05-01 Issue:5 Volume:49 Page:675-682
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Levis Michael¹,Lüning Ulrich¹,Müller Michael²,Schmittel Michael¹,Wöhrle Clemens¹

Affiliation:

1. Chemisches Laboratorium der Universität, Albertstraße 21, D-79104 Freiburg

2. Chemisches Laboratorium der Universität, Albertstraße 21, D-79104

Abstract

Several new 4.7-donor substituted 1.10-phenanthrolines were synthesized and the corresponding tris(1,10-phenanthroline)iron(II) complexes were studied by cyclic voltammetry. All iron(II) complexes showed fully reversible waves at scan rates between 50 and 500 mV/s. For some redox systems the kinetics in their reaction with chlorine was studied. Complexes 7k and 71 significantly extent the potential range of tris(1,10-phenanthroline)iron(II) complexes.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1994-0519/pdf

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