Affiliation:
1. Baker Laboratory, Department of Chemistry and Chemical Biology Cornell University, Ithaca, NY 14853-1301, USA
2. Max-Planck-Institut für Festkörperforschung, D-70569 Stuttgart
Abstract
Abstract
CuCN was investigated by chemical analysis, IR spectroscopy and powder X-ray diffraction. A high-temperature phase of CuCN was identified and structurally characterized by Rietveld refinement. HT-CuCN is isotypic to AgCN (R3m (No. 166), Z = 3, a = 597.109(8), c = 484.33(5) pm, Cu (3a), C/N (6c), z = 0.3915(10) at 77 K) with head-tail disorder of the cyanide anions.
Cited by
24 articles.
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