XPS Spectra of Spin-Triplet Cobalt(III) Complexes

Author:

Brown Dennis G.1,Weser Ulrich1

Affiliation:

1. Anorganische Biochemie, Physiologisch-Chemisches Institut der Universität Tübingen, Hoppe-Seyler-Straße 1, D-7400 Tübingen 1

Abstract

Abstract The X-ray photoelectron spectra of cobalt(III) complexes in an unusual spin triplet state are reported. The binding energies in the 2P spectral region are somewhat low and the spectra exhibit rather strong satellite structure. The Co 2P1/2-CO 2P3/2 separations and satellite intensities appear to be related to the magnetic moments of the complexes as has been suggested previously for cobalt(II) compounds.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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