Bis(trimethylsilyl)-phosphaethene und Tris(trimethylsilyl)silyl-fluorphosphane-Reference-Cited by-同舟云学术

Bis(trimethylsilyl)-phosphaethene und Tris(trimethylsilyl)silyl-fluorphosphane

Published:1984-11-01 Issue:11 Volume:39 Page:1500-1504
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Haase Martin¹,Klingebiel Uwe¹,Skoda Lutz¹

Affiliation:

1. Institut für Anorganische Chemie der Universität Göttingen. Tammannstraße 4, D-3400 Göttingen

Abstract

Abstract Phosphaethenes of the type (Me3Si)2C = P -NRSiMe3 R = C10H15 (7), CMe3 (8), 2.4.6-Me3C6H2 (10)), LiF, and Me3SiF are obtained in the reaction of the aminodifluorophosphanes (3-5) with the lithium salt of tris(trimethylsilyl)methane (1). 10 is isolated as by-product. The main product is F2PC(SiMe3)3 (9). The lithium salt of tris(trimethylsilyl)silan (2) reacts with 3 -6 to give the thermally stable substitution compounds (Me3Si)3Si -PF-NRSiMe3 (11-14). The fluorosilylphosphane Me3Si(CMe3)P -SiFMe - N(SiMe3)2 (15) is formed in the reaction of Me3Si(CMe3)PLi and F2SiMeN (SiMe3)2.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1984-1108/pdf

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