Affiliation:
1. Institut für Physikalische Chemie der Akademie der Wissenschaften, Leninprospect 31, Moskau, Rußland
2. Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-W-7000 Stuttgart 80
Abstract
Gd2Cl3 is electrocrystallized from molten GdCl3 at 900 K with a current efficiency of 70% referring to the reaction 2GdCl3+3e⁻=Gd2Cl3+3Cl-. The reaction is used to determine cocrystallization coefficients for trivalent rare earths and actinoids (Y, Nd, Cm, Pu), divalent lanthanoids (Eu, Yb), and Sr. The oxidation potential for the above reaction is determined as 2.65 ≤ E° ≤ 2.68 V.
Cited by
6 articles.
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