Chlorine-35 NQR Study of a Structural Phase Transition in (ND4)2PdCl6-Reference-Cited by-同舟云学术

Chlorine-35 NQR Study of a Structural Phase Transition in (ND4)2PdCl6

Published:1998-07-01 Issue:6-7 Volume:53 Page:514-517
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Kume Yoshio¹,Asaji Tetsuo²

Affiliation:

1. Department of Basic Science, College of Environmental Health, and Research Institute of Biosciences, Azabu University, 1-17-71 Fuchinobe, Sagamihara, Kanagawa 229, Japan

2. Department of Chemistry, College of Humanities and Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156, Japan

Abstract

Abstract Temperature dependences of 35Cl NQR frequencies and spin-lattice relaxation times were measured at 4.2 to 400 K for natural and deuterated ammonium hexachloropalladate. It was confirmed that only the deuterated salt undergoes a first order phase transition at 30 K. The crystal structure of the low-temperature phase is predicted to be the same as that of the deuterated ammonium hexachloroplatinate and hexachloroplumbate. The mechanism of the deuteration-induced phase transition is discussed.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1998-6-738/pdf

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