Preparation and crystal structure of a non-symmetrical vanadium(II) dimer: tri-μ2-bromido-(hydrogen-tris(3-isopropyl-4-bromopyrazol-1-yl)borato-κ3N,N′,N′′)-tris(tetrahydrofuran-κO)divanadium(II) – tetrahydrofuran (1/1), C34H57BBr6N6O4V2-Reference-Cited by-同舟云学术

Preparation and crystal structure of a non-symmetrical vanadium(II) dimer: tri-μ2-bromido-(hydrogen-tris(3-isopropyl-4-bromopyrazol-1-yl)borato-κ3N,N′,N′′)-tris(tetrahydrofuran-κO)divanadium(II) – tetrahydrofuran (1/1), C34H57BBr6N6O4V2

Published:2020-08-26 Issue:5 Volume:235 Page:1101-1103
ISSN:2197-4578
Container-title:Zeitschrift für Kristallographie - New Crystal Structures
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Author:

Bonitatibus Peter J.¹,Armstrong William H.²,Reiss Guido J.³

Affiliation:

1. Rensselaer Polytechnic Institute, Cogswell Laboratory, Department of Chemistry and Chemical Biology, 110 8th Street, Troy, NY 12180-3590, USA

2. Boston College, Eugene F. Merkert Chemistry Center, Department of Chemistry, 2609 Beacon Street, Chestnut Hill, MA 02467, USA

3. Institut für Anorganische Chemie und Strukturchemie, Lehrstuhl II: Material- und Strukturforschung, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf, Germany

Abstract

AbstractC34H57BBr6N6O4V2, orthorhombic, Pna21 (no. 33), a = 17.198(2) Å, b = 12.9497(11) Å, c = 20.496(2) Å, V = 4564.8(9) Å3, Z = 4, Rgt(F) = 0.0441, wRref(F2) = 0.1093, T = 183(2) K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/downloadpdf/journals/ncrs/235/5/article-p1101.xml

Reference36 articles.

1. Two compounds containing the tris(μ-chloro)hexakis(tetrahydrofuran)divanadium(II) cation. Preparation, structures, and spectroscopic characterization;Inorg. Chem,1985

2. An unusual species containing the mixed-valence {VIII(μ-N)VIV}4+ core obtained by reductive decomposition of Me3SiN3: [VBr2(N3)(dmpe)(μ-N)VBr(dmpe)2];Inorg. Chem,1992

3. N,N,N′,N′-Tetramethylethane-1,2-diaminium tri-μ-chloro-bis[(N,N,N′,N′-tetramethylethane-1,2-diamine)vanadium(II)] tetraphenylborate tetrahydrofuran solvate;Acta Crystallogr,2004

4. Binuclear cationic μ-bromo complexes of vanadium(II);Polyhedron,1988

5. Structural studies of the vanadium (II) and vanadium(III) chloride tetrahydrofuran solvates;Chem. Commun,1983