Affiliation:
1. Centro di studio per la termodinamica ed elettrochimica dei sistemi salini fusi e solidi del CNR c/o Istituto di Chimica Fisica, Università di Pavia (Italy)
Abstract
The electric conductivity and the initial thermoelectric power are determined for the solid solutions (Ag, Na)X (X = Cl, Br) over the whole composition range.
Data drawn from both kinds of measurements allow to approximately estimate the contributions of cation vacancies and interstitial Ag* to the transport process.
Two composition regions are distinguished: 0≦NNaX≦0.6 and 0.7<NNaX<1 where interstitial Ag+ and cation vacancies, respectively, are prevailing.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
10 articles.
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