Thermoelectric Power and Electric Conductivity of the (Ag, Na) Cl and (Ag,Na)Br Solid Solutions

Author:

Magistris A.1,Schiraldi A.1,Chiodelli G.1

Affiliation:

1. Centro di studio per la termodinamica ed elettrochimica dei sistemi salini fusi e solidi del CNR c/o Istituto di Chimica Fisica, Università di Pavia (Italy)

Abstract

The electric conductivity and the initial thermoelectric power are determined for the solid solutions (Ag, Na)X (X = Cl, Br) over the whole composition range. Data drawn from both kinds of measurements allow to approximately estimate the contributions of cation vacancies and interstitial Ag* to the transport process. Two composition regions are distinguished: 0≦NNaX≦0.6 and 0.7<NNaX<1 where interstitial Ag+ and cation vacancies, respectively, are prevailing.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Cited by 10 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Phonon-lifetimes in demixing systems;Journal of Physics: Condensed Matter;2012-05-25

2. Stability of Diffusion Profiles in quasi-binary Solid Solutions (Ag, Na)Cl;Berichte der Bunsengesellschaft für physikalische Chemie;1995-01

3. Thermoelectric power of the high ionic conductivity glasses silver iodide:silver oxide.boron oxide;The Journal of Physical Chemistry;1985-04

4. Thermodynamic properties and thermoelectric power of solid electrolytes;Solid State Ionics;1983-12

5. Ionic Transport Numbers in the Solid Systems (Ag,Na)X (X = Cl,Br);Zeitschrift für Physikalische Chemie;1979-01-01

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