Affiliation:
1. School of Mechanical Engineering , Shanghai Jiao Tong University , Shanghai 200240 , China
2. Department of Mechanical Engineering , Bahauddin Zakariya University , Multan 60800 , Pakistan
3. Department of Mechanical Engineering , University of Engineering and Technology Lahore (FSD Campus) , Faisalabad 38000 , Pakistan
Abstract
Abstract
Selective catalytic reduction (SCR) is now an established NO
x
removal technology for industrial flue gas as well as for diesel engine exhaust gas. However, it is still a big challenge to develop a novel low-temperature catalyst for NH3-SCR of NO
x
, especially at a temperature below 200°C. In the past few years, many studies have demonstrated the potential of iron (Fe)-based catalysts as low-temperature catalysts for NH3-SCR of NO
x
. Herein, we summarize the recent progress and performance of Fe-based catalysts for low-temperature NH3-SCR of NO
x
. Catalysts are divided into three categories: single Fe
x
O
y
, Fe-based multimetal oxide, and Fe-based multimetal oxide with support catalysts. The catalytic activity and selectivity of Fe-based catalysts are systematically analyzed and summarized in light of some key factors such as activation energy, specific surface area, morphology, crystallinity, preparation method and precursor, acid sites, calcination temperature, other metal dopant/substitute, and redox property of catalysts. In addition, H2O/SO2 tolerance and the NH3-SCR reaction mechanism over Fe-based catalysts, including Eley-Rideal and Langmuir-Hinshelwood mechanism, are emphasized. Lastly, the perspectives and future research directions of low-temperature NH3-SCR of NO
x
are also proposed.
Subject
General Chemical Engineering
Reference157 articles.
1. Adapa S, Gaur V, Verma N. Catalytic oxidation of NO by activated carbon fiber (ACF). Chem Eng J 2006; 116: 25–37.
2. Ahmed SN, Baldwin R, Derbyshire F. Catalytic activated reduction carbons of nitric oxide over activated carbons. Fuel 1993; 72: 287–292.
3. Amiridis MD, Wachs IE, Deo G, Jehng J-M, Kim DS. Reactivity of V2O5 catalysts for the selective catalytic reduction of NO by NH3: influence of vanadia loading, H2O, and SO2. J Catal 1996; 161: 247–253.
4. Armenta S, de la Guardia M. Pollutants and air pollution. In: de la Guardia M, Armenta S, editors. Comprehensive analytical chemistry. Amsterdam: Elsevier, 2016: 27–44.
5. Armor JN. Catalytic reduction of nitrogen oxides with methane in the presence of excess oxygen: a review. Catal Today 1995; 26: 147–158.
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