Selective acid-functionalized mesoporous silica catalyst for conversion of glycerol to monoglycerides: state of the art and future prospects

Author:

Hermida Lilis12,Amani Hadis1,Saeidi Samrand34,Zuhairi Abdullah Ahmad1,Rahman Mohamed Abdul1

Affiliation:

1. School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus , 14300 Nibong Tebal , Penang , Malaysia

2. Department of Chemical Engineering , Universitas Lampung , Bandar Lampung 35145 , Lampung , Indonesia

3. Department of Wood and Paper Science, Research Institute of Forests and Rangelands, Agricultural Research, Education and Extension Organization (AREEO) , Tehran , Iran

4. School of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic) , No. 424, Hafez Avenue , 15914, Tehran , Iran

Abstract

Abstract The quest for efficient and selective catalysts for conversion of glycerol monoglyceride is critical for the development of reliable methods for its synthesis. Thus, various types of catalyst and methods of catalyst manufacturing for conversion of glycerol to monoglycerides have been investigated. Acid-functionalized mesoporous catalysts are emerging as highly efficient catalysts for conversion of glycerol into monoglyceride. The incorporation of acid components into different mesoporous silicas for this application is reviewed in this work. The superiority of mesostructure catalysts in comparison to microporous catalysts has been elucidated in terms of accessibility to active sites, pore diffusion, thermal stability of the catalyst and catalyst reusability. Recent direction of novel acid-functionalized mesoporous catalysts development for this application is also critically reviewed.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering

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