Fast Reactions Involving Radical-Cations During their Geminate Recombination as Studied by the OD ESR Method-Reference-Cited by-同舟云学术

Fast Reactions Involving Radical-Cations During their Geminate Recombination as Studied by the OD ESR Method

Published:1985-03-01 Issue:3 Volume:40 Page:239-245
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:
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Author:

Saik V. O.¹,Anisimov O. A.¹,Lozovoy V. V.¹,Molin Yu. N.¹

Affiliation:

1. 1Institute of Chemical Kinetics and Combustion, Novosibirsk 630090, USSR, and Novosibirsk State University, Novosibirsk 630090, USSR

Abstract

The new method of optically detected ESR (OD ESR) of radical-ion pairs has been used to study fast radical-cation reactions in non-polar liquid solutions. Dimeric radical-cations have been observed to occur within the time of geminate recombination with radical-ions; their generation rate has been determined. The spectral line broadening with increasing acceptor concentration has been associated with ion-molecular charge transfer; the rate of this process has also been determined.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1985-0305/pdf

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