Bi2O3/ZnO heterostructured semiconductor nanocomposites: synthesis, characterization and its visible light-induced degradation of methylene blue dye

Author:

Simeyon Velanganni1,Dinesh Ayyar2,Deivatamil Deivanayagam3,Thiruneelakandan Raghavan4,Meena Boominathan Catherin5,Mathavi Manikandan6,Padmapriya Govindaswamy6,Durka Manikandan7,Ayyar Manikandan89,Ansarie AbuZar10,Hashem Mohamed11,Fouad Hassan12

Affiliation:

1. Department of Chemistry , Parvathy’s Arts and Science College (Affiliated to Madurai Kamaraj University, Madurai) , Dindigul , 624002 , Tamil Nadu , India

2. Department of Chemistry , Government Arts College for Men (Autonomous), Affiliated to the University of Madras , Chennai , 600035 , Tamil Nadu , India

3. PG & Research Department of Physics , Thanthai Periyar Government Arts College (Autonomous) , Tiruchirappalli , 620023 , Tamil Nadu , India

4. Department of Chemistry , University College of Engineering, BIT Campus, Anna University , Tiruchirappalli , 620024 , Tamil Nadu , India

5. Department of Chemistry , Bishop Heber College , Tiruchirappalli , 620017 , Tamil Nadu , India

6. Department of Chemistry , Faculty of Arts and Science, Bharath Institute of Higher Education and Research (BIHER) , Chennai , 600073 , Tamil Nadu , India

7. Department of Physics , Bharath Institute of Higher Education and Research (BIHER) , Chennai , 600073 , Tamil Nadu , India

8. Department of Chemistry , Karpagam Academy of Higher Education , Coimbatore , 641021 , Tamil Nadu , India

9. Centre for Material Chemistry , Karpagam Academy of Higher Education , Coimbatore , 641021 , Tamil Nadu , India

10. Department of Obstetrics and Gynecology and Ewha Medical Research Institute , College of Mediciane, Ewha Womens University , Seoul , 07984 , Republic of Korea

11. Department of Dental Health , College of Applied Medical Sciences, King Saud University , P.O Box. 12372 , Riyadh , Saudi Arabia

12. Biomedical Engineering Department , Faculty of Engineering, Helwan University , Helwan , Egypt

Abstract

Abstract In this study, we describe the creation of linked semiconductor nanomaterials, which represents a significant development for photocatalytic applications. A Bi2O3–ZnO hetrostructured thin film was created using the SILAR-CBD deposition technique. In comparison to pure ZnO and Bi2O3, the produced heterostructured thin film showed greater photocatalytic (PCD) activity for the degradation of methylene blue (MB) dye under UV light. The formation of Bi2O3 (monoclinic lattice phase) and ZnO (hexagonal wurtzite phase) are the heterostructured nanomaterials that were generated, according to a powder XRD inspection. An image taken with HR-TEM demonstrates the mixing of nanoparticles and nanorod formations in the Bi2O3/ZnO. The vectorial movement of electrons (e) and holes (h+) between ZnO and Bi2O3 is responsible for the boosted photocatalytic efficiency, which is in turn, accountable for the enhanced photocatalytic activities.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Reference38 articles.

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