Oxokohlenstoffe und verwandte Verbindungen, 31 [1]. 3-Antipyryl-4-hydroxy-cyclobutendion (Antipyrylsemiquadratsäure) und seine Derivate / Oxocarbons and Related Compounds, 31 [1]. 3-Antipyryl-4-hydroxy-cyclobutenedione (Antipyrylsemisquaric Acid) and its Derivatives

Author:

Schmidt Arthur H.1,Kohler Jochen1,Pretsch Ramona1,Freytag-Loringhoven Sarah von1,Wiesert Peter R.1

Affiliation:

1. Fachbereich Chemie und Biologie, Europa Fachhochschule Fresenius, Limburger Straße 2, D-65510 Idstein, Germany

Abstract

Antipyrylsemisquaric chloride (9) has been prepared with excellent yield from antipyrylsemisquaric acid (8) and oxalic dichloride in the presence of dimethylformamide. Reaction of 9 with N and S nucleophiles afforded antipyrylsemisquaric acid derivatives, such as amides 12a - t, 14a - e, 15, hydrazides 18a - e, and thioesters 21a - i.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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