Recent achievements in copper catalysis for C–N bond formation-Reference-Cited by-同舟云学术

Recent achievements in copper catalysis for C–N bond formation

Published:2020-06-25 Issue:8 Volume:92 Page:1181-1199
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:en
Short-container-title:

Author:

Averin Alexei D.¹,Abel Anton S.¹,Grigorova Olga K.¹,Latyshev Gennadij V.¹,Kotovshchikov Yury N.¹,Mitrofanov Alexander Yu.¹,Bessmertnykh-Lemeune Alla²,Beletskaya Irina P.³

Affiliation:

1. Lomonosov Moscow State University , Chemistry , Moscow , Russian Federation

2. ENS de Lyon , Laboratoire de Chimie , Lyon , Rhône-Alpes , France

3. Lomonosov Moscow State University , Chemistry , Leninskie Gory, 1-3 , Moscow , 119991 , Russian Federation

Abstract

Abstract A mini-review describes the development of the catalysis by Cu(I) complexes aimed at the formation of C–N bond at the Lomonosov MSU during 2010s. The main approach employs the amination of aryl and heteroaryl halides with the amines and polyamines, in this direction a great versatility of starting compounds was achieved: adamantane-containing amines, linear diamines, oxadiamines and polyamines, various aryl iodides and bromides, derivatives of pyridine, and quinoline were used for this purpose. In more peculiar cases, the copper catalysis was used for steroids transformations, including vinylation of azoles, wide-spread “click” reactions for the conjugate syntheses, and successful heterogenezation of the copper catalysts were also undertaken.

Funder

Russian Foundation for Basic Research

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2020-0301/pdf

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