Oxygen-17 Nuclear Magnetic Resonance of Organic Solids

Author:

Dong Shuan1,Yamada Kazuhiko1,Wu Gang1

Affiliation:

1. 1Department of Chemistry, Queen's University Kingston, Ontario, Canada K7L 3N6

Abstract

We report solid-state 17O NMR determinations of the oxygen chemical shift (CS) and electric field gradient (EFG) tensors for a series of 17O-enriched organic compounds containing various functional groups. In several cases, analysis of the n O magic-angle-spinning (MAS) and static NMR spectra yields both the magnitude and relative orientations of the 17O CS and EFG tensors. We also demonstrate the feasibility of solid-state 17O NMR as a potentially useful technique for studying molecular structure and hydrogen bonding.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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