Affiliation:
1. Fachbereich 6 Anorganische Chemie der Gerhard-Mercator-Universität, GH Duisburg, D-47048 Duisburg
Abstract
The acid strength of alkanepolysulfonic acids was measured using the correlation between the 29Si NMR shift of the corresponding trimethylsilylester of an acid and the pKS1-value of the acid. Alkanepolysulfonic trimethylsilylesters XHC(SO3-SiMe3)2, X2C(SO3-SiMe3)2, XC(SO3- SiMe3)3 and Me3Si-O3S-(CR2)n-SO3-SiMe3 with X = H, F, Cl, Br, I and R = H, F and n = 1 - 5 were investigated.
Cited by
24 articles.
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