Synthesis, single-crystal structure determination and Raman spectrum of Cu[C(CN)3]2·2 NH3-Reference-Cited by-同舟云学术

Synthesis, single-crystal structure determination and Raman spectrum of Cu[C(CN)3]2·2 NH3

Published:2015-03-01 Issue:3 Volume:70 Page:177-181
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Reckeweg Olaf¹,Schulz Armin²,DiSalvo Francis J.¹

Affiliation:

1. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA

2. Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-70569 Stuttgart, Germany

Abstract

Abstract Transparent, light blue crystals of Cu[C(CN)3]2·2 NH3 were obtained by dissolving Cu[C(CN)3]2 in aqueous ammonia and subsequent evaporation of the solvent under ambient conditions. Cu[C(CN)3]2·2 NH3 crystallizes in the space group C2/c (no. 15, Z = 4) with the cell parameters a = 1291.9(3), b = 753.18(15) and c = 1200.8(2) pm, and β = 92.68(3)°. The nature of the tricyanomethanide anion and the ammonia molecules were verified by Raman spectroscopy. Single crystals of Ag[C(CN)3] and Cu[C(CN)3]2 were synthesized, the known structures were confirmed and their Raman spectra were recorded for the first time for comparison.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2014-0242/pdf

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The unexpected crystal structure of thallium(I) tricyanomethanide Tl[C(CN)₃];Zeitschrift für Naturforschung B;2022-02-08

2. Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH) n (H2O)4– n {C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2);Zeitschrift für Naturforschung B;2018-11-24

3. Synthesis, vibrational spectra and single-crystal structure determination of lithium tricyanomethanide Li[C(CN)3];Zeitschrift für Naturforschung B;2018-02-27