Darstellung und Kristallstruktur von K3Cu3P2 / On the Preparation and Crystal Structure of K3CU3P

Author:

Savelsberg Gerhard1,Schäfer Herbert1

Affiliation:

1. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule Darmstadt

Abstract

Abstract K3CU3P2 was obtained by melting potassium, copper and red phosphorus in an sealed copper vessel. The compound crystallizes trigonally with a = 572 ± 2 pm, c = 1993 ± 3 pm, R3m, Z = 3. The structure analysis revealed nets of puckered 12-membered rings in which the Cu-atoms are linearly coordinated while the P-atoms are located on the apices of trigonal pyramids

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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