Affiliation:
1. Institut für Anorganische und Analytische Chemie, Universität Münster , Corrensstrasse 30 , 48149 Münster , Germany
Abstract
Abstract
Rod-shaped single crystals of Sr4Pt10In21 were prepared from the elements in glassy-carbon crucibles in a high-frequency furnace. The structure of Sr4Pt10In21 was refined from single-crystal X-ray diffractometer data: C2/m, Ho4Ni10Ga21 type, a = 2322.62(7), b = 450.27(2), c = 1958.09(7) pm, β = 133.191(3)°, wR = 0.0464, 3200 F
2 values and 107 variables. The three-dimensional [Pt10In21]δ− polyanionic network is stabilized through substantial Pt–In (269–313 pm Pt–In) and In–In (294–362 pm In–In) bonding. All platinum atoms have slightly distorted tri-capped trigonal prismatic coordination and the two crystallographically independent strontium atoms are located in penta-capped pentagonal prisms.
Reference48 articles.
1. I. Muts, U. Ch. Rodewald, V. I. Zaremba, R. Pöttgen, Z. Naturforsch. 2011, 66b, 1101.
2. P. Villars, K. Cenzual, Pearson’s Crystal Data: Crystal Structure Database for Inorganic Compounds (release 2018/19), ASM International®, Materials Park, Ohio (USA) 2018.
3. R.-D. Hoffmann, R. Pöttgen, Chem. Eur. J. 2000, 6, 600.
4. Ya. M. Kalychak, V. I. Zaremba, R. Pöttgen, M. Lukachuk, R.-D. Hoffmann, in Handbook on the Physics and Chemistry of Rare Earths, Vol. 34 (Eds.: K. A. Gschneider Jr., V. K. Pecharsky, J.-C. Bünzli), Elsevier, Amsterdam, 2005, chapter 218, p. 1.
5. I. R. Muts, V. I. Zaremba, U. Ch. Rodewald, W. Hermes, R. Pöttgen, Z. Anorg. Allg. Chem. 2007, 633, 2725.
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