Ternary Intercalation Compound of Graphite with Aluminum Fluoride and Fluorine-Reference-Cited by-同舟云学术

Ternary Intercalation Compound of Graphite with Aluminum Fluoride and Fluorine

Published:1981-11-01 Issue:11 Volume:36 Page:1419-1423
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Nakajima Tsuyoshi¹,Kawaguchi Masayuki¹,Watanabe Nobuatsu¹

Affiliation:

1. Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Sakyo-ku, Kyoto 606, Japan

Abstract

Abstract A ternary intercalation compound of graphite with AlF3 and F2, CxF(AlF3)y was prepared under fluorine atmosphere at temperatures of 20-400 °C. The typical 1st stage compound has a composition of C6F(AlF3)0,15 with a repeat distance of 940 pm. Rapid progress in the reaction led of the formation of graphite fluoride, (C2F)n. ESCA spectra indicate that the chemical bond between host graphite and intercalated fluorine has nearly covalent nature similar to that for (C2F)n.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1981-1114/pdf

Cited by 34 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Charge-discharge behavior of fluorine-intercalated graphite for the positive electrode of fluoride ion shuttle battery;Electrochemistry Communications;2020-01

2. Microscopic characterization of the C–F bonds in fluorine–graphite intercalation compounds;Journal of Power Sources;2020-01

3. In‐situ structural characterizations of electrochemical intercalation of graphite compounds;Carbon Energy;2019-11-19

4. 13C/19F high-resolution solid-state NMR studies on layered carbon-fluorine compounds;Carbon;2018-11

5. Recent Progress in Graphite Intercalation Compounds for Rechargeable Metal (Li, Na, K, Al)‐Ion Batteries;Advanced Science;2017-06-23