6-Methoxy-3,3’,3’-Trimethylspiro[2H-1-Benzopyran-2,1’[2]Oxaindan]: Separation Of Enantiomers, Circular Dichroism Measurements And Determination Of The Absolute Configuration-Reference-Cited by-同舟云学术

6-Methoxy-3,3’,3’-Trimethylspiro[2H-1-Benzopyran-2,1’[2]Oxaindan]: Separation Of Enantiomers, Circular Dichroism Measurements And Determination Of The Absolute Configuration

Published:2003-08-01 Issue:7-8 Volume:58 Page:443-450
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Voloshina Elena N.¹,Wang Yuekui¹,Voloshina Nikolai A.²,Raabe Gerhard¹,Gais Hans-Joachim¹,Fleischhauer Jörg¹

Affiliation:

1. Institut für Organische Chemie, Rheinisch-Westfälische Technische Hochschule Aachen, Prof.-Pirlet-Strasse, 1, D-52074 Aachen

2. Institute of Physical and Organic Chemistry, Rostov State University, 344090 Rostov on Don, Russia

Abstract

The enantiomers of 6-methoxy-3,3’,3’-trimethylspiro[2H-1-benzopyran-2,1’[2]oxaindan] were separated with the high-pressure liquid chromatography method. Their optical properties were studied experimentally and by quantum-chemical calculations. The absolute configurations of the compounds were determined by comparison of the measured and calculated CD spectra.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-2003-7-810/pdf

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Theoretical Analysis of the Individual Contributions of Chiral Arrays to the Chiroptical Properties of Tris-diamine Ruthenium Chelates;Journal of the American Chemical Society;2009-06-04

2. Polyketides from the marine-derived fungus Ascochyta salicorniae and their potential to inhibit protein phosphatases;Org. Biomol. Chem.;2006

3. An attempt to determine the absolute configuration of two ascolactone stereoisomers with time-dependent density functional theory;Chirality;2006