Slow Lithium Transport in Metal Oxides on the Nanoscale-Reference-Cited by-同舟云学术

Slow Lithium Transport in Metal Oxides on the Nanoscale

Published:2017-06-30 Issue:7-8 Volume:231 Page:1423-1442
ISSN:2196-7156
Container-title:Zeitschrift für Physikalische Chemie
language:en
Short-container-title:

Author:

Uhlendorf Johanna¹,Ruprecht Benjamin²,Witt Elena²,Chandran C. Vinod²,Dörrer Lars¹,Hüger Erwin¹,Strauß Florian¹²³,Heitjans Paul²⁴,Schmidt Harald¹³⁴

Affiliation:

1. Technische Universität Clausthal , Institut für Metallurgie, AG Mikrokinetik , Clausthal-Zellerfeld , Germany

2. Institut für Physikalische Chemie und Elektrochemie , Leibniz Universität Hannover , Hannover , Germany

3. CZM – Clausthaler Zentrum für Materialtechnik , Clausthal-Zellerfeld , Germany

4. ZFM – Zentrum für Festkörperchemie und Neue Materialien , Hannover , Germany

Abstract

Abstract This article reports on Li self-diffusion in lithium containing metal oxide compounds. Case studies on LiNbO3, Li3NbO4, LiTaO3, LiAlO2, and LiGaO2 are presented. The focus is on slow diffusion processes on the nanometer scale investigated by macroscopic tracer methods (secondary ion mass spectrometry, neutron reflectometry) and microscopic methods (nuclear magnetic resonance spectroscopy, conductivity spectroscopy) in comparison. Special focus is on the influence of structural disorder on diffusion.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/zpch-2016-0939/pdf

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