Author:
Plešek Jaromír,Baše Karel,Mareš František,Hanousek František,Štíbr Bohumil,Heřmánek Stanislav
Abstract
Unique properties of metallocarborane sandwich anions of the type [(C2B9H11)2M(III)]- as chemical stability, specific reactivity, very strong acidity of conjugated acids along with an extreme organophility of their salts and a very limited solubility of the salts with organic cations in water are discussed. The application of metallocarboranes to analysis, characterization and isolation of organic bases, including alkaloids, amino acids, amides, etc., from very diluted water solutions is suggested and demonstrated on some examples.
Publisher
Institute of Organic Chemistry & Biochemistry
Cited by
56 articles.
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