Activity Ratios of Lyate Ions in the Water-Alcohol Mixtures

Author:

Pavelek Zdeněk,Mollin Jiří

Abstract

A new method for calculating the activity ratio of lyate ions in the water-alcohol mixtures is proposed on the basis of utilizing the linear relations between the Gibbs energies of ion transfer. The results for the water-methanol, -ethanol, and -2-propanol systems are compared with literature data. At the same time, the individual ionic products of water and alcohol in their mixtures were calculated. The accuracy of the method depends on the accuracy of experimental determination of the Gibbs energies of electrolyte transfer and of ionic products in mixed solvents.

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

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