Kinetics and mechanism of the aquation of a series of mixed-metal oxo-centered trinuclear cations, μ3-oxo-triaqua-hexakis(carboxylato)bis-(chromium(III)(iron(III))+, [ (RCOO)6(H2O)3]+, (R=H, CH3, CH3CH2 and (CH3)2CH) in perchloric acid media
Author:
Affiliation:
1. a Department of Chemistry , University of the West Indies, Mona Campus , Kingston 7, Jamaica, West Indies
Publisher
Informa UK Limited
Subject
Materials Chemistry,Physical and Theoretical Chemistry
Link
https://www.tandfonline.com/doi/pdf/10.1080/00958972.2010.491546
Reference25 articles.
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2. New trinuclear, oxo-centered, basic carboxylate compounds of transition metals. 1. Trichromium(II,III,III) compounds
3. Synthesis, crystal structures and magnetic properties of trinuclear oxo-centered manganese complexes of the general formula [Mn3O(O2CR)6L3]z+ (R=Me, Et, Ph, CH2Cl; L=3-methylpyridine or water z=1, 0)
4. Lattice-engineered micromodulation of intramolecular electron-transfer rates in trinuclear mixed-valence iron acetate complexes
5. Electron Localization and Delocalization in Mixed-Valence Transition Metal Clusters: Structural and Spectroscopic Studies of Oxo-Centered Trinuclear Complexes [Fe3O(OOCCMe3)6(py)3]+/0 and [Mn3O(OOCCMe3)6(py)3]+/0
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