8-Oxoheptafulvene III. One Step Synthesis of Heptafulvalene and Benzoheptafulvalenes

Author:

Asao Toyonobu,Morita Noboru,Kitahara Yoshio

Publisher

Informa UK Limited

Subject

Organic Chemistry

Reference5 articles.

1. 8-oxoheptafulvene. II The reaction with benzophenone and tropones

2. von, W. and joering, E. 1959.Theoretical Organic Chemistry. The Kekule Symposium, 44New York, N. Y.: Academic Press. T. iiukai, II. Tsu-ruta, T, Nakazawa, K. Isobe and K. liirabayashi,Sci. r>epts. Res. Inst. Tohoku Univ. Ser. A.5, 113 (1968); W. M. Jones and C. L. Ennis,J Amer. Chan. Soc.9, 6391 (1969); J. A. Myers, P> C. Joines and W. M. Jones,J. Amer. Chan. Soc.,92, 4740 (1970)

3. We found that the reaction of 2-methoxytropone and its derivatives also gave methoxyheptafulvalenes in a better yields together with oxaazulanone derivatives. The results will appear elsewhere

4. We thank Dr. T. rlachiguchi, Saitama University, for donation of 2, 3-benzotropone

5. Zur Kenntnis der Ketene. Über die Reaktionsfähigkeit des Carbonyls

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1. One hundred years of benzotropone chemistry;Beilstein Journal of Organic Chemistry;2018-05-23

2. The Fulvalenes;European Journal of Organic Chemistry;2005-08

3. [8+2] Cycloaddition of 8-oxoheptafulvene with cycloheptatrieneFe(CO)3: synthesis of tricarbonyl[(2,3,4,5-η)-11-acetoxy-1H-cyclohept[a]azulene]iron;Journal of Organometallic Chemistry;2002-01

4. Fulvalenes, Fulvenes, and Related Molecules:  An ab Initio Study;The Journal of Organic Chemistry;1997-04-01

5. Ketene Cycloadditions;Organic Reactions;1994-06-10

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