Preparation of Aromatic Fluorides Via Diazotization and Photochemically Induced Fluoro-Dediazoniation of Aromatic Amines in Anhydrous Hydrogen Fluoride - Organic Base Solutions

Author:

Yoneda Norihiko,Fukuhara Tsuyoshi,Kikuchi Tetsuo,Suzuki Akira

Publisher

Informa UK Limited

Subject

Organic Chemistry

Reference8 articles.

1. An Improved Procedure for Diazotization Fluoro-Dediazoniation of Anilines Using Organic Base-HF Agents

2. The Use of Hexafluorophosphoric Acid in the Schiemann Reaction1

3. Dediazoniations of Arene Diazonium Ions in Homogenous Solution. Part IV: Change-over from a heterolytic to a homolytic mechanism in 2,2,2-trifluoroethanol pyridine mixtures

4. Ionenpaareffekte bei der Photolyse und Thermolyse von Aryldiazonium-tetrafluoroboraten

5. Clear evidence for the formation of Ar+from ArN2+by irradiation has not been obtained yet in our experiments. One electron transfer mechanism in the formation of Ar+from initialy formed Ar by irradiation might be an adequate explanation for our reactions. We are grateful to Prof. T. Sonoda (Kyushu Univ.) for his helpful discussions.

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2. Generation of 1,2-Difluorobenzene via a Photochemical Fluorodediazoniation Step in a Continuous Flow Mode;Organic Process Research & Development;2023-01-16

3. Synthesis of fluorinated halonitrobenzenes and halonitrophenols using tetrafluoroethylene and buta-1,3-dienes as starting building blocks;Russian Chemical Bulletin;2021-11

4. Diazotization of Amines and Dediazoniation of Diazonium Ions;PATAI'S Chemistry of Functional Groups;2009-12-15

5. 2-Fluoroaniline;Encyclopedia of Reagents for Organic Synthesis;2006-04-15

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