Removal of reactive black 5 in water using adsorption and electrochemical oxidation technology: kinetics, isotherms and mechanisms

Abstract

AbstractIn this work, a novel graphite intercalation compound (GIC) particle electrode was used to investigate the adsorption of Reactive Black 5 (RB5) and the electrochemical regeneration in a three-dimensional (3D) electrochemical reactor to recover its adsorptive capacity. Various adsorption kinetics and isotherm models were used to characterise the adsorption behaviour of GIC. Several adsorption kinetics were modelled using linearised and non-linearised rate laws to evaluate the viability of the sorption process. Studies on the selective removal of RB5 dyes from binary mixture in solution were evaluated. RSM optimisation studies were integrated with ANOVA analysis to provide insight into the significance of selectivity reversal from the salting effect of textile dye solution on GIC adsorbent. A unique range of adsorption kinetics and isotherms were used to evaluate the adsorption process. Non-linear models best simulated the kinetic data in the order: Elovich > Bangham > Pseudo-second-order > Pseudo-first-order. The Redlich–Peterson isotherm was calculated to have a dye loading capacity of 0.7316 mg/g by non-linear regression analysis. An error function analysis with ERRSQ/SSE of 0.1390 confirmed the accuracy of dye loading capacity predicted by Redlich–Peterson isotherm using non-linear regression analysis. The results showed that Redlich–Peterson and SIPS isotherm models yielded better fitness to experimental data than the Langmuir type. The best dye removal efficiency achieved was ~ 93% using a current density of 45.14 mA/cm2, whereas the highest TOC removal efficiency achieved was 67%.