Improved coverage factors for expanded measurement uncertainty calculated from two estimated variance components

Author:

Rostron Peter D.,Fearn Tom,Ramsey Michael H.

Abstract

AbstractMeasurement uncertainty (MU) arising at different stages of a measurement process can be estimated using analysis of variance (ANOVA) on replicated measurements. It is common practice to derive an expanded MU by multiplying the resulting standard deviation by a coverage factor k. This coverage factor then defines an interval around a measurement value within which the value of the measurand, or true value, is asserted to lie for a desired confidence level (e.g. 95 %). A value of k = 2 is often used to obtain approximate 95 % coverage, although k = 2 will be an underestimate when the standard deviation is estimated from a limited amount of data. An alternative is to use Student’s t-distribution to provide a value for k, but this requires an exact or approximate degrees of freedom (df). This paper explores two different methods of deriving an appropriate k in the case when two variances from an ANOVA (classical or robust) need to be combined to estimate the measurement variance. Simulations show that both methods using the modified coverage factor generally produce a confidence interval much closer to the desired level (e.g. 95 %) when the data are approximately normally distributed. When these confidence intervals do deviate from 95 %, they are consistently conservative (i.e. reported coverage is higher than the nominal 95 %). When outlying values are included at the level of the larger variance component, in some cases the method used for robust ANOVA produces confidence intervals that are very conservative.

Publisher

Springer Science and Business Media LLC

Reference8 articles.

1. International organization for standardization. ISO/IEC Guide 98–3:2008(en) Uncertainty of measurement—Part 3: Guide to the expression of uncertainty in measurement (GUM:1995). ISO: Geneva, Switzerland. https://bbn.isolutions.iso.org/obp/ui#iso:std:iso-iec:guide:98:-3:ed-1:v2:en5

2. Ramsey MH, Ellison SLR, Rostron PD (eds.) (2019) Eurachem/EUROLAB/CITAC/Nordtest/AMC Guide: Measurement uncertainty arising from sampling: a guide to methods and approaches. Second Edition, Eurachem (2019). ISBN (978–0–948926–35–8). https://www.eurachem.org/index.php/publications/guides/musamp

3. Ramsey MH (2020) Challenges for the estimation of uncertainty of measurements made in situ accreditation and quality assurance. J Qual Comp Reliab Chem Meas 26(4):183–192. https://doi.org/10.1007/s00769-020-01446-4

4. Lyn JA, Ramsey MH, Coad S, Damant AP, Wood R, Boon KA (2007) The duplicate method of uncertainty estimation: are eight targets enough? Analyst 132:1147–1152. https://doi.org/10.1039/B702691A

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