Author:
Liu Ning,Mei Lefu,Bin Jianxiong,Zhang Ze,Peng Zhijian
Abstract
AbstractNovel scheelite structures of Li2Ca(WO4)2, Li2Ca2(WO4)(SiO4), and LiCa2(WO4)(PO4) fluorescent materials were successfully prepared using a high-temperature solid-phase process. The compounds were characterized by X-ray diffraction and energy dispersive spectroscopy. The tests revealed that the substitution of [WO4]2− by [SiO4]4− or [PO4]3− tetrahedron in tungstate had no significant influence on the crystal structure of the Li2Ca(WO4)2. When Dy3+ ions were introduced as an activator at an optimum doping concentration of 0.08 mol%, all of the as-prepared phosphors generated yellow light emissions, and the emission peak was located close to 576 nm. Replacing [WO4]2− with [SiO4]4− or [PO4]3− tetrahedron significantly increased the luminescence of the Li2Ca(WO4)2 phosphors. Among them, the LiCa2(WO4)(PO4):0.08Dy3+ phosphor had the best luminescence properties, decay life (τ = 0.049 ms), and thermal stability (87.8%). In addition, the as-prepared yellow Li2Ca(WO4)2:0.08Dy3+, Li2Ca2(WO4)(SiO4):0.08Dy3+, and LiCa2(WO4)(PO4):0.08Dy3+ phosphor can be used to fabricate white light emitting diode (LED) devices.
Publisher
Springer Science and Business Media LLC
Subject
Ceramics and Composites,Electronic, Optical and Magnetic Materials
Cited by
24 articles.
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