Cationic and neutral copper(I) iodide cluster MOFs derived from tridentate N-donor functionalized P(V) ligands: synthesis, structure and photophysical properties

Author:

Yadav Ashok,Deshmukh Mahesh S,Boomishankar RamamoorthyORCID

Funder

Science and Engineering Research Board

Publisher

Springer Science and Business Media LLC

Subject

General Chemistry

Reference20 articles.

1. (a) Shan X-C, Jiang F-L, Yuan D-Q, Zhang H-B, Wu M-Y, Chen L, Wei J, Zhang S-Q, Pan J and Hong M-C 2013 A multi-metal-cluster MOF with $$\text{Cu}_{4}\text{I}_{4}$$ Cu 4 I 4 and $$\text{Cu}_{6}\text{S}_{6}$$ Cu 6 S 6 as functional groups exhibiting dual emission with both thermochromic and near-IR character Chem. Sci. 4 1484; (b) Zhan S-Z, Li M, Zhou X-P, Wang J-H, Yang J-R and Li D 2011 When $$\text{Cu}_{4}\text{I}_{4}$$ Cu 4 I 4 cubane meets $$\text{Cu}_{3}(\text{pyrazolate})_{3}$$ Cu 3 ( pyrazolate ) 3 triangle: Dynamic interplay between two classical luminophores functioning in a reversibly thermochromic coordination polymer Chem. Commun. 47 12441; (c) Amoore J J M, HantonL R and Spicer M D 2003 Banded ribbons of $$\text{Cu}_{6}\text{I}_{6}$$ Cu 6 I 6 hexamers and multimodal thioetherpyrazine ligands linked by self-complementary $$\text{N}\cdots \text{H}{-}\text{C}$$ N ⋯ H - C synthons Dalton Trans. 1056; (d) Peng R, Wu T and Li D 2005 A chiral coordination polymer containing copper(I) iodide layer composed of intersecting CuI $$_\text{n}$$ n helices CrystEngComm 7 595; (f) Tzeng B-C and Chang T-Y 2009 Cryst. Growth Des. 9 5343; (e) Deshmukh M S, Yadav A, Pant R and Boomishankar R 2015 Thermochromic and Mechanochromic Luminescence Umpolung in Isostructural Metal–Organic Frameworks Based on $$\text{Cu}_{6}\text{I}_{6}$$ Cu 6 I 6 Clusters Inorg. Chem. 54 1337

2. (a) Kitagawa H, Ozawa Y and Toriumi K 2010 Flexibility of cubane-like $$\text{Cu}_{4}\text{I}_{4}$$ Cu 4 I 4 framework: Temperature dependence of molecular structure and luminescence thermochromism of $$[\text{Cu}_{4}\text{I}_{4}(\text{PPh}_{3})_{4}]$$ [ Cu 4 I 4 ( PPh 3 ) 4 ] in two polymorphic crystalline states Chem. Commun. 46 6302; (b) Shan X-C, Jiang F-L, Yuan D-Q, Wu M-Y, Zhang S-Q and Hong M-C 2012 The unusual thermochromic NIR luminescence of Cu(I) clusters: Tuned by Cu–Cu interactions and packing modes Dalton Trans. 41 9411

3. (a) Kang Y, Wang F, Zhang J and Bu X 2012 Luminescent MTN-Type cluster–organic framework with 2.6 nm cages J. Am. Chem. Soc. 134 17881; (b) Prochowicz D, Justyniak I, Kornowicz A, Kaczorowski T, Kaszkur Z and Lewiński 2012 Construction of a Porous Homochiral Coordination Polymer with Two Types of $$\text{Cu}_\text{n}\text{I}_\text{n}$$ Cu n I n Alternating Units Linked by Quinine: A Solvothermal and a Mechanochemical Approach Chem. Eur. J. 18 7367

4. (a) Kim,T H, Shin Y W, Jung J H, Kim J S and Kim J 2008 Crystal-to-Crystal Transformation between Three CuI Coordination Polymers and Structural Evidence for Luminescence Thermochromism Angew. Chem. Int. Ed. 47 685; (b) Liu Z, Djurovich P I, Whited M T and Thompson M E 2012 $$\text{Cu}_{4}\text{I}_{4}$$ Cu 4 I 4 Clusters Supported by $$\text{P}^{\wedge}\text{N-type}$$ P ∧ N-type Ligands: New Structures with Tunable Emission Colors Inorg. Chem. 51 230; (c) Blake A J, Brooks N R, Champness N R, Crew M, Davison A, Fenske D, Gregory D H, Hanton L R, Hubberstey P and Schröder M 2001 Topological isomerism in coordination polymers Chem. Commun. 1432; (d) Hu S and Tong M-L 2005 Rational design and construction of the first tetrahedral net with photoluminescent $$\text{Cu}_{4}\text{I}_{4}$$ Cu 4 I 4 cubane cluster as the tetrahedral node Dalton Trans. 1165; (e) Chen Y, Li H-X, Liu D, Liu L-L, Li N-Y, Ye H-Y, Zhang Y and Lang J-P 2008 Solvent effects on the assembly of $$[\text{Cu}_{2}\text{I}_{2}]$$ [ Cu 2 I 2 ] -or $$[\text{Cu}_{4}\text{I}_{4}]$$ [ Cu 4 I 4 ] -based coordination polymers: Isolation, structures, and luminescent properties Cryst. Growth Des. 8 3810; (f) Pike R D, Reinecke B A, Dellinger M E, Wiles A B, Harper J D, Cole J R, Dendramis K A, Borne B D, Harris J L and Pennington W T 2004 Bicyclic phosphite esters from pentaerythritol and dipentaerythritol: New bridging ligands in organometallic and inorganic chemistry Organometallics 23 1986

5. (a) Lu J Y 2003 Crystal engineering of Cu-containing metal–organic coordination polymers under hydrothermal conditions Coord. Chem. Rev. 246 327; (b) Ouellette W, Prosvirin A V, Chieffo V, Dunbar K R, Hudson B and Zubieta J 2006 Solid-state coordination chemistry of the Cu/triazolate/X system (X= F-, Cl-, Br-, I-, OH-, and $$\text{SO}_{4}^{2-}$$ SO 4 2 - ) Inorg. Chem. 45 9346; (c) Wu T, Li M, Li D and Huang X-C 2008 Anionic $$\text{Cu}_{{\rm n}}\text{I}_{{\rm n}}$$ Cu n I n cluster-based architectures induced by in situ generated N-alkylated cationic triazolium salts Cryst. Growth Des. 8 568; (d) Prajapati R K and Verma S 2011 Adenine coordination around a $$\text{Cu}_{6}\text{I}_{6}$$ Cu 6 I 6 core Inorg. Chem. 50 3180

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